7. Han Rausing and family
£5,400 million - Packaging
This is the man who helped develop the Tetra Pak, revolutionising the packaging of milk and fruit juices. Since then he's invested in other environmentally-friendly packaging materials.
He also ranks as one of Britain's most charitable donors, thanks to his donations of over £146 million in recent years, which could account for his fall from his position at No 6 on last year's list.